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Non-Newtonian



Mixing Xanthan Gum

Until now, the continuous medium in this report has been water. The CFD program handles many different types of rheologies. For Xanthan Gum, a power-law correlation works well. The ACUSOLVE code represents this as:

mu = mu0 * ( (eta^2) * I2 )^( (n-1)/2 )

mu0 = reference viscosity

eta = a time constant

I2 = second invariant of the strain rate tensor - which is basically gammadot^2 (from CFD)

n = shear thinning exponent 

In this case, the operative constants were mu0 = 2.5 kg/m s, a shear-thinning exponent of 0.7, and the time constant was set to 1.0. According to our estimates, the apparent viscosity around the impeller tip region is in the ballpark of 200 cPs, the material bulk is about 2500 cPs. We used 1000 kg/m3 for the density.

Xanthan Gum is used as an emulsifier, lubricant, suspending agent, and/or a thickener. We ran our Xanthan Gum, at 1500 RPM and with a flow rate of 750 GPM in our 10" Schedule 40 pipe. We used the HGR.

hgr model.jpg (51967 bytes)
Figure 25: Tracer study at 650 GPM and 1500 RPM of Xanthan Gum with the HGR. Based on the colors in the outlet, the distribution of residence time is wide. The light green area shows an iso-surface where the Eddy Viscosity is about 50% of the total. The maximum Eddy Viscosity is 0.010 m2/s, so the green surface represents 0.005 m2/s. It appears that all of the tracer particles go through this high shearing region. Internals other than the impellers and shaft are not shown.

Both pictures from Figure 25 are under the same conditions. It is interesting to see that the Eddy Viscosity surface is not symmetrical. This has to do with the rotational direction of the impeller and the flow. On the right hand side, the volume is larger. This is the side where the impeller blades are moving against the current. On the left hand side, the blades are moving with the current.

The lower impeller is slightly visible. This means that it is not completely engulfed in this high-energy zone. Table 1 also shows that the lower impeller has a lower power number.

The particles are added below the lower impeller. The picture on the right shows that the tracers are swept toward the back Z-plate wall before being forced up. Then it appears that every tracer particle goes into this high-energy zone. It does not appear that this high viscosity will have a problem mixing in a Process intensifier.

Figure 26 compares this non-Newtonian case with water. The residence time distributions look fairly similar. The fastest and longest times are about the same. Some particles in the Xanthan Gum only take one second longer to leave the device. The statistics are given in Table 6. The Eddy Viscosity volume for the water case is much larger than the Xanthan Gum (Fig 26). Obviously the shear drops quicker away from the impellers than does water. The power numbers are essentially the same (see Table 7). The pressure drop was essentially the same, too. The Xanthan Gum is essentially behaving like water inside the Process Intensifier.

HGR Np(bottom) Np (top) Np(total) ΔP
Xanthan Gum 2.5 3.5 5.9 3.9 (26690)
Water 2.4 3.5 5.9 3.9 (26890)
Table 7: Power numbers for the HGR impellers and the pressure drop in psi (Pa).


HGR – 650 GPM – 1750 RPM - Water HGR – 750 GPM – 1500 RPM – Xanthan Gum
Figure 26: Residence Time Distribution, tracer study, and pressure distribution for water and non-Newtonian Xanthan Gum in the HGR. Internals other than the impellers and shaft are not shown.

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